Inorganic Chemistry [GAME OVER, SCUM WIN]
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Binary metal hydrides
Many transition metals form compounds with hydrogen, called binary hydrides because they only contain two elements. These compounds are invariably insoluble in all solvents. They often exhibit metal-like electrical conductivity. Many are nonstoichiometric compounds. Electropositive metals (Ti, Zr, Hf, Zn) and some other metals form hydrides with the stoichiometry MH or sometimes MH2 (M = Ti, Zr, Hf, V, Zn). The best studied are the binary hydrides of palladium, which readily forms a limiting monohydride. In fact, hydrogen gas diffuses through Pd windows via the intermediacy of PdH.
Ternary metal hydrides
Ternary metal hydrides have the formula AxMHn, where A+ is an alkali or alkaline earth metal cation, e.g. K+ and Mg2+. A celebrated example is K2ReH9, a salt containing two K+ ions and the ReH92− anion. Other homoleptic metal hydrides include the anions in Mg2FeH6 and Mg2NiH4. Some of these anionic polyhydrides satisfy the 18-electron rule, many do not. Because of their high lattice energy, these salts are typically not soluble in any solvents, a well known exception being K2ReH9.
Coordination complexes
The most prevalent hydrides of the transition metals are metal complexes that contain a mix of other ligands in addition to hydride. The range of coligands is large. Virtually all of the metals form such derivatives. The main exceptions include the late metals silver, gold, cadmium, and mercury, which form few or unstable complexes with direct M-H bonds. Examples of an industrially useful hydrides are HCo(CO)4 and HRh(CO)2(PPh3)3, which are catalysts for hydroformylation.
The first molecular hydrides of the transition metals were first reported in the 1930s by Walter Hieber and coworkers. They described H2Fe(CO)4 and HCo(CO)4, After a hiatus of several years, and following the release of German war documents on the postulated role of HCo(CO)4 in hydroformylation, several new hydrides were reported in the mid-1950s by three prominent groups in organometallic chemistry: HRe(C5H5)2 by Wilkinson, HMo(C5H5)(CO)3 by Fischer, and HPtCl(PEt3)2 by Chatt. Thousands of such compounds are now known.
Cluster hydrides
Like hydrido coordination complexes, many clusters feature terminal (bound by one M-H bond) hydride ligands. Hydride ligands can also bridge pairs of metals, as illustrated by [HW2(CO)10]−. The cluster H2Os3(CO)11 features both terminal and doubly bridging hydride ligands. Hydrides can also span the triangular face of a cluster. Triply-bridging hydride ligands occupy six of the eight Cu3 faces in the clusters H6Cu6[PR3]6. In the cluster [Co6H(CO)15]−, the hydride is "interstitial", occupying a position at the center of the Co6 octahedron.
Vote Count 1.15
Bins - 2 (Lying Cat, Sonic Boom)
hiplop - 5 (vezokpiraka, ZZZX, Flubbernugget, Cerberus v666, Shakira Confirmed)
Shakira Confirmed - 1 (Mac)
Sonic Boom - 3 (mastin2, Ankamius, Tere)
Wickedestjr - 1 (Bins)
ZZZX - 2 (hiplop, Jaqen Hghar)
Not Voting: ika, Kari, Wickedestjr
Lying Cat and Mac have been prodded.
mastin2 is LA until June 16th.
9 to lynch. Deadline is in (expired on 2015-06-17 23:00:25)The distance between insanity and genius is measured only by success.- Bins
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Hey, let's play the bad news good news game again.
Bad news: I probably won't get fully caught up. It got late fast. Time flew way faster than it should have.
Good news: I know that if I don't start doingsomethingtonight, I'll not get it done at all.
"Uhh...that doesn't sound like good news."
Well, no, it's absolutely terrible, but the thing that makes it good news is that I'm actually going to be doing something to stop it from getting worse at the very least. Get as much done as I can.
...Worse news, though: I have completely disassociated myself with the game. I don't remember a thing.
I remember where I was, though, so I'm continuing reading from 22.My academy.
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Reading Wicked as prob-town for what it's worth, though. (Which means he's almost certainly scum. )
Right. Sonic Boom is scum. I remember that, too.↑ Sonic Boom wrote:Mastina you are not a scumhunting god, not since your hiatus no
Not that I'd need to since this series of posting would be enough on its own.
(Wouldn't surprise me at all if Metal Sonic's quoting the evil overlord list in his topic. )
Also, pretty dang sure this is ZX as town. (But Sonic Boom pushing them this way as scum certainly contributes to some of that.)
Not arrogance. Experience.↑ Shakira Confirmed wrote:At the surface, this sounds really arrogant.
There are certain things that when they happen.
You just fundamentally know.
That either the player is scum.
Or something has gone horribly,horriblywrong.
The former being the infinitely more likely of the two.
This is one of them.
(Still think Shakira is a Sonic buddy.)My academy.
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Because I'm arrogant.
Aaaannd, the votes I don't approve of continue.
(Also, Flubb MAY be scum. Hard to say for sure.)
Well there's always Shakira to bus you!↑ Sonic Boom wrote:also, I'm pretty worried that the players on the wagon on my slot right now mostly *looks like town*My academy.
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Don't question the mastin. It leads to bad things happening.
Well, half aint bad.
Also, Jaqen's not a concern of mine to sort. Not right now. That'll happen later. Basically, the way to read Jaqen is reads getting better = town, reads getting worse = scum. Gun to head would be town though. (Though that's also aided by having too many scumreads. How many scum are there in this game again? Four? Five? I think I have at least that many suspicions. )My academy.
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Nope! I'm just hoping that
I'mnot being dumb in trustingyouto be town.
Huh. Funny you mention that. The bit about seeming fake.↑ Shakira Confirmed wrote:She just seems fake in a lot of posts. Is anyone town reading her?
There are players in this game I'd apply that to, but I'm certainly not one of them.
Well, yes. I admit that means between you/hiplop/Shakira that means it's unlikely you're all scum too unless you're going all L4D on us, but I happen to think that of the three, you're the most likely to be scum and from there I can figure out which of them is likely to be a buddy.↑ Metal Sonic wrote:lmfao, hiplop's vote is terrible as fuck, kill it
(Psst. It means your read on Sonic is wrong.)↑ Cerberus v666 wrote:Sonic Boom - 6 (mastin2, Ankamius, Shakira Confirmed, Tere, Jaqen Hghar, hiplop)
Thoughts on the above? i see two of my stronger town reads(shakira and jaqen) voting for my other strong town read. Ank is nulltown, hiplop nullscum, mastin null null.My academy.
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(BTW in case it wasn't obvious Ank is also a townread of mine, and while I don't remember what my thoughts were on Tere I THINK they were positive, so that's why the wagon save for Shakira and hiplop looks good.)Take care, and be safe.
Yeah, Tere's town.
Very well could be, yes. (The alternative is scum theatrics.)↑ Jaqen Hghar wrote:^scum setting up compromise lynch
(Also, as much as I <3 Bins, it should be obvious, yes I do think she's scum. )
Which means you should have no problem sheeping me on it!↑ Lying Cat wrote:I'll admit to being a bit mystified on the Sonic wagon. Jaqen votes them for being dismissive. Mastin's sure because they were not trusting her on make, which is interesting. Ank's case seems the clearest, Sonic misrepping ank and saying he's being a sheep. Shak appears to not have shared any reasons, although I get the feeling it's the Ank thing from what goes on in the thread there. Tere votes for "little things". And Hiplop's already been discussed.
Of this, I think that Ank is probably town. The outrage at being misrepped feels more likely from town than scum and I'm reading it as very genuine. Shakira's vote feels like buddying Ank, and honestly Shakira or hiplop is probably the scum there if there's scum on the wagon. I liked early mastin in this game. She seems to not be able to explain anything she's thinking, as opposed to not wanting to, which is minor townfeels. That and my super secret mastin-and-sthar8 tell didn't give me scumvibes. Tere's interactions with ika make her town and ika slightly on the scum side of null. Overall, this feels like a townled wagon. Which doesn't necessarily mean it's right, but is reassuring as to it's validity.My academy.
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Yeah, not interested in lynching hiplop today.
That Bins wagon is actually really, really strong. Like, legitimately scarily strong. I mean, the other big wagons are good, it's just that they don't have the same magic attached to them.
VOTE: Bins.
/40. Should stop here, though. I'm losing my mental energy.My academy.
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Think I can compile a readslist, though.
Mac
Lying Cat
ZZZX
Ankamius
Tere
Cerberusv666
Jaqen Hghar
Wickedestjr
vezokpiraka
Kari <--This is the nullline.
ika
hiplop
Shakira Confirmed
Flubbernugget
Bins
Sonic Boom
I'll continue tomorrow.My academy.
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ika
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↑ mastin2 wrote:Hey, let's play the bad news good news game again.
Bad news: I probably won't get fully caught up. It got late fast. Time flew way faster than it should have.
Good news: I know that if I don't start doingsomethingtonight, I'll not get it done at all.
"Uhh...that doesn't sound like good news."
Well, no, it's absolutely terrible, but the thing that makes it good news is that I'm actually going to be doing something to stop it from getting worse at the very least. Get as much done as I can.
...Worse news, though: I have completely disassociated myself with the game. I don't remember a thing.
I remember where I was, though, so I'm continuing reading from 22.
mastin is town.
also smells like a typical -ZZZX post lmaoImplosion: I see ZZZX was lynched. For shame, people. For shame.
The Bulge: ZZZX is ZZZX
Get to know a ZZZX: http://forum.mafiascum.net/viewtopic.php?f=61&t=58733- ZZZX
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I am not liking Hiplop, still didnt quote hte posts in question is trying to build a wagon on my cus ~gut~ . Even if dont do it that far and I am the most random gut player here...
eitherway Bins reading hiplop as town is giving me da weird vibes, there is some "scum wouldnt do that" but thats too dumb
Eitherway that hiplop flips i feel that bins is scummy now.
discuss.Implosion: I see ZZZX was lynched. For shame, people. For shame.
The Bulge: ZZZX is ZZZX
Get to know a ZZZX: http://forum.mafiascum.net/viewtopic.php?f=61&t=58733- Sonic Boom
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↑ ZZZX wrote:I am not liking Hiplop, still didnt quote hte posts in question is trying to build a wagon on my cus ~gut~ . Even if dont do it that far and I am the most random gut player here...
eitherway Bins reading hiplop as town is giving me da weird vibes, there is some "scum wouldnt do that" but thats too dumb
Eitherway that hiplop flips i feel that bins is scummy now.
discuss.
Agreed. That's why I voted bins but Titus changed the vote back so OK - Sonic Boom
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