Inorganic Chemistry [GAME OVER, SCUM WIN]

[Jaqen Hghar]

First, it's a counter wagon to hiplop (meaning scum need to pick one or the other).

A man is noting this misrepresentation. Bins wagon is coming first. With hiplop having more votes and being pushed with easier agreement, a man is pretty sure scum are already choosing their favored wagon. This one is on that wagon...

[Sonic Boom]

umm, no you're wrong. hiplop wagon came first

[Sonic Boom]

i started hiplop wagon here:

lmfao, hiplop's vote is terrible as fuck, kill it

VOTE: hiplop

subsequently from my point of view (my reads), hiplop wagon was entirely town driven

at this point, there were 0 bins voters

Ionization Energy of Transition Metals

A transition metal’s ionization energy is related to the energies of its d orbitals, its ease of oxidation, and its basicity. In simplest terms, the greater a metal’s ionization energy, the harder it is to pull an electron from it. Thus, metal centers with high ionization energies exhibit low basicity (or nucleophilicity) and are resistant to oxidation. Trends in ionization energy are more complex than atomic size trends, as the plot below amply demonstrates.

The first thing we may notice is that in general, ionization energy increases as we move from left to right across a row. Notable dips occur at row 1, group 10 (Ni) and row 3, group 7 (Re). However, the general trend is consistent with our previous notion that electronegativity increases as we move left-to-right across a row. As for trends down a group, it’s difficult to discern anything useful in the graph above. What we can say (considering second and higher ionization potentials, not shown) is that higher oxidation states are more accessible to third-row metals. Easy way to remember this: OsO₄ is a stable reagent that reacts only with alkenes; RuO₄ is prepared in situ and ravages alkenes and alcohols; FeO₄ has never been observed.

We’ll touch on trends in acidity/basicity again in a later post on hydride ligands, but they tend to follow the trends in bond strength described below: basicity increases (and acidity decreases) as we move down a group, generally.

Vote Count 1.8

Cerberus v666 - 2 (Lying Cat, Flubbernugget)
Flubbernugget - 1 (Wickedestjr)
hiplop - 1 (Sonic Boom)
Shakira Confirmed - 1 (Mac)
Sonic Boom - 6 (mastin2, Ankamius, Shakira Confirmed, Tere, Jaqen Hghar, hiplop)
vezokpiraka - 1 (ZZZX)

Not Voting: Bins, Cerberus v666, ika, Kari, vezokpiraka

mastin2 is LA until June 16th.

9 to lynch. Deadline is in (expired on 2015-06-17 23:00:25)

so a man must maintain his memory

[Jaqen Hghar]

Bins - 4 (Lying Cat, mastin2, Jaqen Hghar, Wickedestjr)
hiplop - 6 (vezokpiraka, ZZZX, Flubbernugget, Cerberus v666, Shakira Confirmed, Sonic Boom)
Lying Cat - 1 (Bins)
Shakira Confirmed - 1 (Mac)
Sonic Boom - 2 (Ankamius, Tere)
ZZZX - 1 (hiplop)

Not Voting: ika, Kari

Ank, Tere, hiplop must needs be fixing their vote. Kari and ika must needs be making one. Mac- is a vanity vote really the place to be?

I kind of feel if Bins has a useful and proveable day action, she should consider claiming

Lying Cat - 1 (Bins)

That one is using her day power- unoriginally on the first member of her wagon.

[Jaqen Hghar]

Vote Count 1.3

Bins - 2 (Wickedestjr, Jaqen Hghar)
Cerberus v666 - 1 (ZZZX)
ika - 1 (ika)
Mac - 3 (Shakira Confirmed, Flubbernugget, Sonic Boom)
mastin2 - 1 (hiplop)
Shakira Confirmed - 3 (Flames682, vezokpiraka, Mac)
Sonic Boom - 3 (mastin2, Bins, Ankamius)

A man is well aware of that which is transpiring and though the votes are vanishing, the pressure is not. Bins is still the first wagon with hiplop being the counter and coming with opportune timing so that when the Bins wagon is reforming it can be misrepresented as a counter to hiplop when just the opposite is true. Thanks for stepping up to claim starting that counterwagon, Titusscum.

[vezokpiraka]

Vote Count 1.3

Bins - 2 (Wickedestjr, Jaqen Hghar)
Cerberus v666 - 1 (ZZZX)
ika - 1 (ika)
Mac - 3 (Shakira Confirmed, Flubbernugget, Sonic Boom)
mastin2 - 1 (hiplop)
Shakira Confirmed - 3 (Flames682, vezokpiraka, Mac)
Sonic Boom - 3 (mastin2, Bins, Ankamius)

A man is well aware of that which is transpiring and though the votes are vanishing, the pressure is not. Bins is still the first wagon with hiplop being the counter and coming with opportune timing so that when the Bins wagon is reforming it can be misrepresented as a counter to hiplop when just the opposite is true. Thanks for stepping up to claim starting that counterwagon, Titusscum.

You think hiplop is a counterwagon to bins? What?

Who thinks hiplop is town raise your hand and say why.

[Jaqen Hghar]

A man would like to know how it isn't?

[Jaqen Hghar]

Hiplop wagon is forming just as votes slide off Bins originally (though Bins pressure is continuing with more and more voicing concern for that slot). A man is thinking that is the perfect time for scum to be forming a counter to the suspicion on their scum partner. Hiplop isn't scum. The speed and ease of the until push as well as reasons a man is already giving are showing that one is town.

Scum aren't easy to build a wagon on
Scum don't bounce their vote all over the place on D1 (it's counterintuitive for scum to draw attention to themselves, especially in D1, in such a manner)
His ISO is screaming easy mislynch

[Jaqen Hghar]

*initial push

[vezokpiraka]

Hiplop wagon is forming just as votes slide off Bins originally (though Bins pressure is continuing with more and more voicing concern for that slot). A man is thinking that is the perfect time for scum to be forming a counter to the suspicion on their scum partner. Hiplop isn't scum. The speed and ease of the until push as well as reasons a man is already giving are showing that one is town.

Scum aren't easy to build a wagon on
Scum don't bounce their vote all over the place on D1 (it's counterintuitive for scum to draw attention to themselves, especially in D1, in such a manner)
His ISO is screaming easy mislynch

And you think bins is actually scum?

Also you can't seriously call 2 votes on someone a wagon.

[Jaqen Hghar]

Two votes + suspicion a man is naming a wagon, yes. Is this one not reading outside of ISO's to gain the context he has obviously missed? And no. A man isn't

thinking

Bins is scum. A man is certain Bins is scum.

[Jaqen Hghar]

A man is further finding it no coincidence vezok's vote is bookended by scum-Sonic (who is moving their vote to the end of the wagon to be less obvious and play up "hydra dissonance" out of desperation for a town read) and ZZZX who is also certain scum because that one is probably the easiest player on site to read once you analyze his <town PR, vanilla, scum> plays as he is having a unique style for playing each role.

Lynch Binscum today
Lynch ZZZX scum tomorrow
When a man is right on those (in particular Z)- lynch Sonic D3

Someone else can find #4. A man isn't too sure about his initial read on Cerberus and is seeing a couple of other, better options.

Yes, before it is being asked, a man is definitely lining up lynches. As such, he is much and more content in being flashed lynched if the town is finding that necessary- so long as it is coming with the solemn promise to then follow a man's lineup when he is flipping town.

[Bins]

We can lynch me and I can get an apology from Jaqen and it will be worth it.

My PR isn't that strong. I don't mind if my lynch gives us information.

That said, I don't want die... but I don't want this fucking death tunnel on me anymore. >.>
Jaqen might even be scum holy shit if it weren't for the fact I've only had this done to me by Titus and Sakura before and they were town when they did it.

I will probably switch to hiplop to survivalism vote but I won't like it.

[Bins]

Jaqen, realize if you're town, you're really not letting yourself be open to any fucking signs that I'm town. You're WRONG.

If you're scum, w/e.

[vezokpiraka]

Yeah. Jaqen is living in his own fantasy.

I'm not up for lynching anyone else except hiplop today.

[Sonic Boom]

A man is further finding it no coincidence vezok's vote is bookended by scum-Sonic (who is moving their vote to the end of the wagon to be less obvious and play up "hydra dissonance" out of desperation for a town read) and ZZZX who is also certain scum because that one is probably the easiest player on site to read once you analyze his <town PR, vanilla, scum> plays as he is having a unique style for playing each role.

Lynch Binscum today
Lynch ZZZX scum tomorrow
When a man is right on those (in particular Z)- lynch Sonic D3

Someone else can find #4. A man isn't too sure about his initial read on Cerberus and is seeing a couple of other, better options.

Yes, before it is being asked, a man is definitely lining up lynches. As such, he is much and more content in being flashed lynched if the town is finding that necessary- so long as it is coming with the solemn promise to then follow a man's lineup when he is flipping town.

a man will look like a fool if neither of the above flip scum

[Sonic Boom]

Vote Count 1.3

Bins - 2 (Wickedestjr, Jaqen Hghar)
Cerberus v666 - 1 (ZZZX)
ika - 1 (ika)
Mac - 3 (Shakira Confirmed, Flubbernugget, Sonic Boom)
mastin2 - 1 (hiplop)
Shakira Confirmed - 3 (Flames682, vezokpiraka, Mac)
Sonic Boom - 3 (mastin2, Bins, Ankamius)

A man is well aware of that which is transpiring and though the votes are vanishing, the pressure is not. Bins is still the first wagon with hiplop being the counter and coming with opportune timing so that when the Bins wagon is reforming it can be misrepresented as a counter to hiplop when just the opposite is true. Thanks for stepping up to claim starting that counterwagon, Titusscum.

and a man should remember that bins was a counter wagon to me

so is bins the scum counterwagon or what.

[Jaqen Hghar]

Dissect this "fantasy" so a man can slam you with evidence, vezok. Or, less confrontationally, what part are you having a hard part following?

A man isn't caring how he is looking, Titus. In fact- you of all people- how could a girl ever have the notion a man is caring how he looks?

[Sonic Boom]

The Shielding Effect

An atom (assuming its atomic number is greater than 2) has core electrons that are extremely attracted to the nucleus in the middle of the atom. However the number of protons in the nucleus are never equal to the number of core electrons (relatively) adjacent to the nucleus. The number of protons increase by one across the periodic table, but the number of core electrons change by periods. The first period has no core electrons, the second has 2, the third has 10, and etc. This number is not equal to the number of protons. So that means that the core electrons feel a stronger pull towards the nucleus than any other electron within the system. The valence electrons are farther out from the nucleus, so they experience a smaller force of attraction.

Shielding refers to the core electrons repelling the outer rings and thus lowering the 1:1 ratio. The nucleus has "less grip" on the outer electrons and are shielded from them.

Shielding describes the amount of screening from nuclear charge that one electron can do with respect to its neighboring electrons. Electrons that have greater penetration can get closer to the nucleus and effectively block out the charge from electrons that have less proximity. For example, Z_eff is calculated by subtracting the magnitude of shielding from the total nuclear charge. The value of Z_eff will provide information on how much of a charge an electron actually experiences.

Because the order of electron penetration from greatest to least is s, p, d, f; the order of the amount of shielding done is also in the order s, p, d, f.

Since the 2s electron has more density near the nucleus of an atom than a 2p electron, it is said to shield the 2p electron from the full effective charge of the nucleus. Therefore the 2p electron feels a lesser effect of the positively charged nucleus of the atom due to the shielding ability of the electrons closer to the nucleus than itself, (i.e. 2s electron).

These electrons that are shielded from the full charge of the nucleus are said to experience an effective nuclear charge (Z_eff) of the nucleus, which is some degree less than the full nuclear charge an electron would feel in a hydrogen atom or hydrogenlike ions. The effective nuclear charge of an atom is given by the equation:

Z_eff=Z−S

where

Z is the atomic number (number of protons in nucleus) and
S is the shielding constant
We can see from this equation that the effective nuclear charge of an atom increases as the number of protons in an atom increases. Therefore as we go from left to right on the periodic table the effective nuclear charge of an atom increases in strength and holds the outer electrons closer and tighter to the nucleus. This phenomena can explain the decrease in atomic radii we see as we go across the periodic table as electrons are held closer to the nucleus due to increase in number of protons and increase in effective nuclear charge.

Vote Count 1.1

ika - 1 (Sonic Boom)
Mac - 1 (Ankamius)
mastin2 - 3 (Wickedestjr, hiplop, Gorkington)
Shakira Confirmed - 4 (Flames682, vezokpiraka, ZZZX, Mac)
Sonic Boom - 3 (mastin2, Shakira Confirmed, Flubbernugget)

Not Voting: Cerberus v666, ika, Jaqen Hghar, Lying Cat, Tere

9 to lynch. Deadline is in (expired on 2015-06-17 23:00:25)

the man should read really fucking carefully


cause im not titus

[Jaqen Hghar]

Sonic was an RVS wagon, Bins was not. Try again.

[Sonic Boom]

Dissect this "fantasy" so a man can slam you with evidence, vezok.

im going to dissect the fantasy that bins was a "wagon that came first"

[Sonic Boom]

Sonic was an RVS wagon, Bins was not. Try again.

oh really?

but mastina and shakira parked their votes on me even longer than you call your scumread on bins

so you try again

[Sonic Boom]

Vote Count 1.8

Cerberus v666 - 2 (Lying Cat, Flubbernugget)
Flubbernugget - 1 (Wickedestjr)
hiplop - 1 (Sonic Boom)
Shakira Confirmed - 1 (Mac)
Sonic Boom - 6 (mastin2, Ankamius, Shakira Confirmed, Tere, Jaqen Hghar, hiplop)
vezokpiraka - 1 (ZZZX)

Not Voting: Bins, Cerberus v666, ika, Kari, vezokpiraka

mastin2 is LA until June 16th.

9 to lynch. Deadline is in (expired on 2015-06-17 23:00:25)[/color]

you call the 6 votes on me rvs?

i dont see and bins votes

do you want to justify

[Jaqen Hghar]

A man is conceding he should have picked up on the "fool" keyword when skimming the pedit

[Jaqen Hghar]

Sonic was an RVS wagon, Bins was not. Try again.

oh really?

but mastina and shakira parked their votes on me even longer than you call your scumread on bins

And? Still an RVS wagon. Those are often leaving their RVS parked until finding a real target.